Ctrl as primary modifier. The full Slack shortcut set on Linux uses Ctrl throughout. Channel navigation, quick switcher, message composition, search, and workspace switching all follow this pattern.
Quick switcher. Ctrl+K opens the quick switcher, jump to any channel, DM, or workspace by name. This works the same as on Windows.
Desktop environment conflicts. As with other Linux applications, a small number of Ctrl combinations may be captured by GNOME, KDE, or another desktop environment before Slack receives them. Ctrl+K and most Slack shortcuts are unlikely to conflict, but if something doesn't respond, check your DE's global keyboard settings.
Message editing and navigation. Up Arrow in the compose field edits the most recent message. Ctrl+[ and Ctrl+] navigate back and forward through channel history.
Workspace switching. Ctrl+number keys switch between Slack workspaces directly.